We have tutorials on setting up IMAP/POP accounts for major e-mail clients, including Thunderbird, Outlook, Android and Outlook iOS.
Certain clients, such as http://windows.microsoft.com/pt-br/windows-live/essentials-other#essentials=overviewother Windows Live Mail, might require manual setup.
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Remember to always mark the option to "Require authentication" (sometimes referred to as "My server requires SMTP authentication").
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